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Showing 1 to 3 of 3 for “"Alkyl iodide"”.
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New Strategies in Radical Chemistry and Their Application to the Construction of C(sp3)–C(sp3) Bonds in the Giese Reaction
… merges two electrophilic components (an alkyl halide and an acceptor) in the presence of a silane and visible light irradiation. Under these mild and extraordinarily simple conditions, visible light is anticipated to facilitate initiation derived from an interaction between the haloalkane …
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Accurate ionic bond energy measurements with TCID mass spectrometry and imaging PEPICO spectroscopy
… reactions of several energy selected 1-alkyl iodide cations n-C<sub>n</sub>H<sub>2n+1</sub>I<sup>+</sup> → C<sub>n</sub>H<sub>2n+1</sub><sup>+</sup> + I, (n = 2-5). The 0 K appearance energies of the iodine-loss fragment ions were determined to be 9.836 ± 0.010, 9.752 ± 0.010, 9.721 ± …
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Sustainable strategies for alcohol halogenation
Alkyl halides appear widely in the structures of medicinal compounds and as key synthetic precursors in the pharmaceutical industry. Bimolecular nucleophilic substitution reactions of alcohols are commonly employed in the formation of new carbon–halogen bonds. However, achieving substitution at the …