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Showing 1 to 4 of 4 for “"Alkyl aromatic"”.

  1. MASS SPECTROMETRIC INVESTIGATIONS OF STRUCTURALLY DIAGNOSTIC ION-MOLECULE REACTIONS AND OF MOLECULAR STRUCTURES OF ASPHALTENES

    … separation and characterization of saturated, alkyl aromatic, and polycyclic aromatic hydrocarbon constituents of crude oil. The most common MS/MS method involves collision-activated dissociation of mass-selected ions. Additionally, MS/MS strategies utilizing functional-group or isomer specific …

    purdue-thes Repository record for MASS SPECTROMETRIC INVESTIGATIONS OF STRUCTURALLY DIAGNOSTIC ION-MOLECULE REACTIONS AND OF MOLECULAR STRUCTURES OF ASPHALTENES (opens in a new tab)

  2. Radical additions of hydrocarbons, ethers and acetals to alkenes via allyl transfer reaction: A new chain reaction for C-H bond functionalization

    … compounds for the functionalization of various alkyl aromatic hydrocarbons is demonstrated. Kinetic studies were performed to observe the efficiency of the new chain reaction compared to the previously reported studies with allyl-bromides. We recently discovered that these allyl substrates are …

    vt Repository record for Radical additions of hydrocarbons, ethers and acetals to alkenes via allyl transfer reaction: A new chain reaction for C-H bond functionalization (opens in a new tab)

  3. Bulky cyclopentadienyl chromium complexes as ethene trimerisation catalyst precursors

    … ligands, of the type, C₅Ph₄RH (R = H, alkyl, aromatic or substituted aromatic group) were synthesised. Four routes were investigated. (i) Making use of an in situ generated bis-lithium intermediate, resulting in the formation of 1 ,2,3,4,5-pentaphenyl cyclopenta-1 ,3-diene and 1 …

    cape-town Repository record for Bulky cyclopentadienyl chromium complexes as ethene trimerisation catalyst precursors (opens in a new tab)

  4. Hydrocarbon Functionalization via a New Free Radical-Based Condensation Reaction

    … radical to substituted alkenes. Other than alkyl aromatics (PhCH3, PhCH(CH3)2), other substrates (i.e., 2- propanol, phenyl cyclopropane) were also tested for this allylation reaction. The magnitude and scope of these reactions, and their synthetic utility is discussed.

    vt Repository record for Hydrocarbon Functionalization via a New Free Radical-Based Condensation Reaction (opens in a new tab)