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Showing 1 to 2 of 2 for “"Absolute asymmetric synthesis"”.
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Mechanistic studies on the asymmetry amplifying, autocatalytic Soai reaction
… transformation is peerless in its efficiency for asymmetric autocatalysis and sensitivity to initial chiral imbalances, making it a sui generis example of a reaction predisposed to evolve toward homochirality. Enantiopure products are obtained in three reaction cycles even with calculated …
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Homochiral Crystals for Selective Synthesis
… crystallized as conglomerates. They were used in absolute asymmetric synthesis and oxidized enantioselectively. The oxidations resulted in a selectivity of > 98% without the use of a chiral catalyst. One of the Ru(II) complexes isomerizes when exposed to light. Four new phases, containing one or …