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Showing 1 to 7 of 7 for “"ALLYLIC C––H AMINATION"”.
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New frontiers in allylic C––H amination via palladium/sulfoxideoxazoline catalysis
Direct allylic C––H functionalization of terminal olefin represents an orthogonal approach to traditional methods to build C––O, C––N and C—C bond due to less oxidation state manipulation and synthetic overhead. In particular, site, chemo- and stereoselective methods for Pd(II)-catalyzed allylic …
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Development of palladium catalyzed intramolecular allylic C―H amination and oxidation towards pharmacological motifs
… has made significant developments in the area of allylic C―H oxidation and functionalization reactions. Using these methodologies, a variety of pharmacologically relevant small molecules have been synthesized in highly efficient sequences that minimized overall step counts as well as increasing …
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Linear allylic C-H oxidation: methods and utility
… group tolerance, and streamlining utility of our allylic C-H oxidation chemistry. In general, functional groups are installed in complex molecules through the advent of sequential C-C bond forming reactions. This chemistry is not only well known, but has been employed for decades, resulting in the …
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C—H oxidation reactions: development and application
… the development of the first general, linear allylic C—H amination reaction, as well as applications of a biomimetic non-heme iron catalyst towards generating diverse oxidation products and exploring biological pathways. Linear allylic amines are a common motif found in many organic molecules; …
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Synthetic diversity in C-H activation: development of selective and efficient C-H functionalization reactions
… the development of novel C−H oxidation and amination reactions as new strategies for simplifying and diversifying synthetic sequences. First, harnessing the abundance of α-olefins as starting materials, palladium (II) catalysis is used to effect a divergent intramolecular allylic C−H …
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C(sp3)-H aminations under first row transition metal catalysis
… to introduce nitrogen (e.g. Mannich, reductive amination) often rely on pre-existing functionality and require additional transformations such as oxidation state changes and/or protecting group maniuplations. C—H amination represents a powerful alternative synthetic strategy. This approach …
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Expanding the scope of allylic C—H aminations via electrophilic palladium(II) catalysis
Submission published under a 24 month embargo labeled 'Closed Access', the embargo will last until 2026-08-01