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Showing 1 to 2 of 2 for “"ACC auxiliary"”.

Asymmetric α-Alkylation of Acyclic Ketones Utilizing Chiral Nonracemic N-Amino Cyclic Carbamate Hydrazones

Huynh, Uyen 1986-University of Houston2017

… of ketones using N-Amino cyclic carbamate (ACC) chiral auxiliaries is described. ACC alkylation delivers excellent stereoselectivity and yields, with a camphor-derived ACC auxiliary exhibits the highest stereoselectivities. A full account of this ACC method is discussed herein, including the …

houston Repository record for Asymmetric α-Alkylation of Acyclic Ketones Utilizing Chiral Nonracemic N-Amino Cyclic Carbamate Hydrazones (opens in a new tab)
The Anti Selective Aldol Addition of Ketones to Aldehydes Mediated by N-Amino Cyclic Carbamate Chiral Auxiliaries and Its Use in the Asymmetric Total Synthesis of (+)- and (-)-Mefloquine Hydrochloride

Knight, John D.2012

… by the use of chiral N-amino cyclic carbamate (ACC) auxiliaries. Under certain conditions, this transformation not only exhibits near perfect anti selectivity and enantioselectivity but also does so via thermodynamic control. Simple manipulation of the reaction conditions allows for the …

duke Repository record for The Anti Selective Aldol Addition of Ketones to Aldehydes Mediated by N-Amino Cyclic Carbamate Chiral Auxiliaries and Its Use in the Asymmetric Total Synthesis of (+)- and (-)-Mefloquine Hydrochloride (opens in a new tab)