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Showing 1 to 7 of 7 for “"3-dipolar cycloaddition"”.
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Synthesis Towards Fulminic Acid and Its Derivatives in 1, 3-Dipolar Cycloaddition Reactions.
<p>A new approach to fulminic acid cycloadditions has been developed. At reduced temperatures, fulminic acid is generated <em>in situ</em> and undergoes 1, 3-diploar cycloaddition reactions with dipolarophiles to form isoxazolines and/or its dimers. This procedure represents a novel, safe general …
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The progress towards the total synthesis of (ent)-MPC1001
… with the development of a novel asymmetric [1-3]-dipolar cycloaddition utilizing a vinyl silane and a chiral lactone template. The mechanism of the cycloaddition was investigated and the cyclized product can be elaborated in 6 steps to the A-B-C ring system of the MPC family of natural products. …
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IMPROVED SYNTHESIS OF 3-ARYL-ISOXAZOLES AS INTERMEDIATES FOR NOVEL G-QUADRUPLEX BINDING ANTI-TUMOR AGENTS
… fused aromatic rings using the nitrile oxide cycloaddition (NOC) revealed that modification of the method of Bode, Hachisu, Matsuura and Suzuki (BHMS), was far superior to that of the enamine method. Utilization of either triethyl amine as a base or sodium enolates of diketone, ketoester and …
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IMPROVED SYNTHESIS OF 3-ARYL-ISOXAZOLES AS INTERMEDIATES FOR NOVEL G-QUADRUPLEX BINDING ANTI-TUMOR AGENTS
… fused aromatic rings using the nitrile oxide cycloaddition (NOC) revealed that modification of the method of Bode, Hachisu, Matsuura and Suzuki (BHMS), was far superior to that of the enamine method. Utilization of either triethyl amine as a base or sodium enolates of diketone, ketoester and …
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Functionalization, growth and applications of single wall carbon nanotubes
… method achieved include amidation, 1 ,3-dipolar cycloaddition and nitration, with the latter providing SWNTs that are very soluble in water and alcohol. Both microwave-induced and supercritical carbon dioxide approaches were also used to prepare and study the formation of ceramic (silicon …
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Interfacial Nitrone 1,3-Dipolar Cycloadditions for Modification of Monolayer Protected Gold Nanoparticles
… as a template and its ability to undergo the 1,3-dipolar cycloaddition reaction with a series of nitrones under ambient and high-pressure conditions. Expanding the scope of this reaction to the investigation in synthesizing a nitrone modified-MPN and examine its ability to undergo the 1,3-dipolar …
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Ex-Chiral-Pool-Synthese von 5-Aminopiperidylessigsäuren über eine Tandem-Wittig-1,3-dipolare Cycloaddition
Ziel dieser Arbeit war es die Tandem-Wittig-1,3-dipolare Cycloaddition auf a-Hydroxyurethanderivate zu übertragen und so chirale, nichtracemische b-Amino-piperidylacetatderivaten in möglichst hoher Diastereomerenreinheit darzustellen. Diese Aminopiperidinderivate sollten mit …