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Showing 1 to 9 of 9 for “"3-dipolar"”.
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Synthesis Towards Fulminic Acid and Its Derivatives in 1, 3-Dipolar Cycloaddition Reactions.
… 1, 3-diploar cycloaddition reactions with dipolarophiles to form isoxazolines and/or its dimers. This procedure represents a novel, safe general method for the one-step generation of fulminic acid, which complements existing potentially explosive protocols.</p>
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Reactividad de complejos semisandwich de rodio con ligandos alquenilfosfina frente a nucleófilos y sistemas insaturados. Reacciones de cicloadicción 1, 3-dipolar y acoplamiento c-c
… al estudio de las reacciones de cicloadición 1,3-dipolar de los complejos [Rh(η5-C5Me5)(N3)2(PR3)] (PR3 = ADIP, ADPP y PPh3) y dipolarófilos como alquinos activados y nitrilos que conducen a derivados triazolato o tetrazolato respectivamente, observándose diferentes patrones de reactividad …
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The progress towards the total synthesis of (ent)-MPC1001
… with the development of a novel asymmetric [1-3]-dipolar cycloaddition utilizing a vinyl silane and a chiral lactone template. The mechanism of the cycloaddition was investigated and the cyclized product can be elaborated in 6 steps to the A-B-C ring system of the MPC family of natural products. …
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IMPROVED SYNTHESIS OF 3-ARYL-ISOXAZOLES AS INTERMEDIATES FOR NOVEL G-QUADRUPLEX BINDING ANTI-TUMOR AGENTS
… enolates of diketone, ketoester and ketoamide dipolarophiles gave much higher yields as well as fewer by-products from the NOC. Here-in is reported the improved synthesis of 3-aryl-isoxazoles via an adaption of the BHMS method. Included in this report is the crystallographic data for Ethyl …
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IMPROVED SYNTHESIS OF 3-ARYL-ISOXAZOLES AS INTERMEDIATES FOR NOVEL G-QUADRUPLEX BINDING ANTI-TUMOR AGENTS
… enolates of diketone, ketoester and ketoamide dipolarophiles gave much higher yields as well as fewer by-products from the NOC. Here-in is reported the improved synthesis of 3-aryl-isoxazoles via an adaption of the BHMS method. Included in this report is the crystallographic data for Ethyl …
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Interfacial Nitrone 1,3-Dipolar Cycloadditions for Modification of Monolayer Protected Gold Nanoparticles
… as a template and its ability to undergo the 1,3-dipolar cycloaddition reaction with a series of nitrones under ambient and high-pressure conditions. Expanding the scope of this reaction to the investigation in synthesizing a nitrone modified-MPN and examine its ability to undergo the 1,3-dipolar …
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Functionalization, growth and applications of single wall carbon nanotubes
… method achieved include amidation, 1 ,3-dipolar cycloaddition and nitration, with the latter providing SWNTs that are very soluble in water and alcohol. Both microwave-induced and supercritical carbon dioxide approaches were also used to prepare and study the formation of ceramic (silicon …
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Ex-Chiral-Pool-Synthese von 5-Aminopiperidylessigsäuren über eine Tandem-Wittig-1,3-dipolare Cycloaddition
Ziel dieser Arbeit war es die Tandem-Wittig-1,3-dipolare Cycloaddition auf a-Hydroxyurethanderivate zu übertragen und so chirale, nichtracemische b-Amino-piperidylacetatderivaten in möglichst hoher Diastereomerenreinheit darzustellen. Diese Aminopiperidinderivate sollten mit …