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Showing 1 to 1 of 1 for “"3-R-hydroxybutyryl oxo CoA analogs"”.
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Design and synthesis of mechanistic probes for polyhydroxybutyrate synthases
… of PHB synthases (PhaCs). The first type is oxo analogs in which the sulfur in the coenzyme A (CoA) thioester has been replaced with an oxygen atom. A series of 3-R-hydroxybutyryl oxo CoA analogs, (HB)[subscript]nOCoA (n = 1, 2 and 3), were synthesized chemoenzymatically in good yields. Two …