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Showing 1 to 1 of 1 for “"β-boronic ester"”.
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Diastereoselective α-Alkylation of Chiral β-Borylated Esters
… for the α-alkylation of chiral β-borylated esters. We propose that standard deprotonation of chiral β-borylated esters with lithium diisopropylamide (LDA) leads to the formation of a boron"ate" intermediate that upon treatment with an alkylation reagent collapses to provide chiral α, …