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Showing 1 to 2 of 2 for “"α-Diazo-β-keto sulfones"”.
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Investigation of catalyst effects in enantioselective copper- and rhodium-mediated transformations of α-diazocarbonyl compounds
… the synthesis and reactivity of a series of α-diazocarbonyl compounds with particular emphasis on the use of copper-bis(oxazoline)-mediated enantioselective C–H insertion reactions leading to enantioenriched cyclopentanone derivatives. Through the use of additives, the enantioselectivity …
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Synthetic and stereochemical aspects of enantioselective copper catalysed C-H insertion reactions leading to cyclopentanones and sultones
… thesis describes the synthesis of a series of α-diazocarbonyl compounds including α-diazoβ-keto sulfones, α-diazo-β-keto phosphine oxides, 2-diazo-1,3-diketones and αdiazosulfonates, and their reactivity in intramolecular copper–bis(oxazoline)–NaBARF catalysed C–H insertion reactions. Excellent …