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Showing 1 to 3 of 3 for “"α-Alkylated ketones"”.
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New methods for the asymmetric synthesis of α-alkylated ketones and 1,3-amino alcohols
… and natural products contain α-functionalised ketones or simple derivatives thereof. Furthermore, chiral α-alkylated ketones are useful synthons and have found widespread use in total synthesis. The asymmetric alkylation of ketones represents one of the most powerful and longstanding procedures …
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Studies in asymmetric synthesis I the asymmetric alpha-alkylation of N,N-dimethylhydrazones II the synthesis of 1,3-amino alcohols via the aldol-Tishchenko reaction
… and natural products contain α- functionalised ketones or simple derivatives thereof. Furthermore, chiral α- alkylated ketones are useful synthons and have found widespread use in total synthesis. The asymmetric alkylation of ketones represents one of the most powerful and longstanding …
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Studies in asymmetric synthesis: I. the asymmetric α-alkylation of N,N-dimethylhydrazones II. the asymmetric aldol-Tishchenko reaction of (S)-tert-butanesulfinyl imines for the introduction of 2, 3, 4 and 5 new chiral centres in one pot
… research. Part 1 The asymmetric α-alkylation of ketones is one of the most fundamental yet challenging transformations in organic chemistry. Recently a new methodology to furnish enantiomerically enriched α-alkylated ketones was developed within the McGlacken group using N,N-dimethylhydrazones as …