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Showing 1 to 2 of 2 for “"[2,3]-Wittig Rearrangement"”.
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Viridiofungins and xeniolide F: target oriented synthesis using different rearrangement reactions of a common substrate class
… of xeniolide F. In both cases, sigmatropic rearrangements of α-allyloxy substituted α,β-unsaturated esters are employed: for the viridiofungin ester synthesis a [2,3]-Wittig rearrangement and for the xeniolide F synthesis a catalytic asymmetric Claisen rearrangement CAC. For both …
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Phase transfer catalysis: catalyst screening, reaction development, and mechanism analysis
… base in addition to the development of a [2,3]-Wittig rearrangement under phase transfer catalysis (PTC) reaction conditions was investigated. Supplementing these studies, a deeper understanding of the PTC mechanism was sought for the alkylation of phenol. In regards to the asymmetric PTC (APTC) …