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Virginia Polytechnic Institute

Atomic size factor and the Cr3O-type compound in the Cr-Si-Sn ternary system

Abstract

dc:description.abstract

An investigation was conducted to determine if Sn atoms could be substituted for Si atoms in the compound Cr₃Si. Prom size factor considerations, the feasibility that this substitution should occur seemed reasonable. However, attempts to make the substitution were unsuccessful. A model of the Cr₃O-type compounds, of which Cr₃Si is a representative, is proposed. From this model substitution of a Sn atom for a Si atom would require the formation of a double bond. The possibility of this double bond being unable to form may explain the unsuccessful attempts to make the above substitution.

Degree

thesis:*
Name thesis:degree_name
Master of Science
Level thesis:degree_level
masters
Discipline thesis:degree_discipline
Metallurgical Engineering
Department dc:contributor.department
Metallurgical Engineering
Grantor dc:publisher
Virginia Polytechnic Institute
Year dc:date.issued
1961

Author and committee

dc:creator, dc:contributor.*
Author dc:creator
  • Barton, Eugene Edward

Rights

dc:rights
Statement dc:rights
  • In Copyright
Language dc:language.iso
en_US

Identifiers

dc:identifier.*
Handle dc:identifier.uri
http://hdl.handle.net/10919/76352
OAI identifier oai:identifier
oai:vtechworks.lib.vt.edu:10919/76352

Chain of custody

source
Harvested from
Virginia Tech
Base URL
vtechworks.lib.vt.edu/oai/request
Last updated
2026-07-22
Source record
OAI-PMH GetRecord
related terms
citation

Barton, Eugene Edward. Atomic size factor and the Cr3O-type compound in the Cr-Si-Sn ternary system. masters thesis, Virginia Polytechnic Institute, 1961. http://hdl.handle.net/10919/76352