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Virginia Tech

An infrared absorption study of lithium in silicon

Abstract

dc:description.abstract

Lithium, lithium oxide, and the group V elements, phosphorus, arsenic, antimony, and bismuth, when present in silicon as impurities, act as "shallow" donors (2, 7, 11). These donors have electrons which are bound so loosely that they may be thermally excited into the conduction band at less than room temperature. The excited bound states and, less precisely, the ground states of these electrons are understood within the framework of the shallow donor theory. A transition from the 1S(E+T₁) state of lithium oxide, which lies 7.7± .1 mev above its ground state, to the 2P<sup>±</sup> state was observed. When phosphorus and lithium were both present as donors in silicon, the phosphorus peaks normally occurring at 34.4 mev, 2P<sub>O</sub> and 39.2 mev, 2P<sup>±</sup>, seemed to be split by .8 ± .1 mev. An upper limit of 10¹⁴/ cc was observed for the oxygen content of zone refined silicon using Pell's (15) value for the dissociation constant, C.

Degree

thesis:*
Name thesis:degree_name
Master of Science
Level thesis:degree_level
masters
Discipline thesis:degree_discipline
Physics
Department dc:contributor.department
Physics
Grantor dc:publisher
Virginia Tech
Year dc:date.issued
1967

Author and committee

dc:creator, dc:contributor.*
Author dc:creator
  • Wood, John Herbert

Rights

dc:rights
Statement dc:rights
  • In Copyright

Identifiers

dc:identifier.*
Dc Identifier Other
etd-10252006-141830
OAI identifier oai:identifier
oai:vtechworks.lib.vt.edu:10919/45322

Chain of custody

source
Harvested from
Virginia Tech
Base URL
vtechworks.lib.vt.edu/oai/request
Last updated
2026-07-22
Source record
OAI-PMH GetRecord
related terms
citation

Wood, John Herbert. An infrared absorption study of lithium in silicon. masters thesis, Virginia Tech, 1967. http://hdl.handle.net/10919/45322