Abstract
dc:description.abstractThe scope and limitations of aromatic diazines undergoing nucleophilic substitution reactions occurring via a radical-chain Sʀɴ1 mechanism were investigated. The study was conducted on a series of mono- and dihalogenated aromatic diazines interacting with various ketone enolates in ammonia. Results indicate that this previously unrecognized reaction pathway in these nitrogen heterocycles is easily obtained and should prove of great synthetic utility in preparation of substituted diazines.
Degree
thesis:*- Name thesis:degree_name
- Ph. D.
- Level thesis:degree_level
- doctoral
- Discipline thesis:degree_discipline
- Chemistry
- Department dc:contributor.department
- Chemistry
- Grantor dc:publisher
- Virginia Tech
- Year dc:date.issued
- 1979
Author and committee
dc:creator, dc:contributor.*- Author dc:creator
-
- Carver, David Reginald
- Chair dc:contributor.committeechair
-
- Wolfe, James F.
- Committee members dc:contributor.committeemember
-
- Hudlicky, M.
- Bell, Harold M.
- Taylor, Larry T.
- Sanzone, George
Rights
dc:rights- Statement dc:rights
-
- In Copyright
- Licence dc:rights.uri
- Language dc:language.iso
- en
Identifiers
dc:identifier.*- Dc Identifier Other
- etd-11302012-040014
- OAI identifier oai:identifier
- oai:vtechworks.lib.vt.edu:10919/40381