Gas- and solid-mixing behavior in a vibrated-bed microreactor with rapid switching of catalyst between gas atmospheres

A cold-flow vibated-bed microreactor system, operating at the room temperature and atmospheric pressure, was built and tested. The purpose of this microreactor was to simulate gas- and solid-mixing in a hot-flow microreactor system. The latter is being developed to study carbon deposition rates for continuous Fischer-Tropsch synthesis from a low H₂:CO gas with rapid switching of catalyst between gas atmospheres. The cold-flow microreactor consisted of three chambers with vertical sliding baffles that shift catalyst between the smaller, center reaction chamber and two outer chambers. The results show that the solid mixing within each chamber is essentially complete within one second after transfer of catalyst. The solid mixing was independent of gas flow and gas flow rate. Results of gas-mixing studies show that gas transfer between chambers of the microreactor was due to the transfer of gas within the interstices of transferred catalyst particles. During rapid baffle-switching intervals, complete gas mixing within each chamber occurred. The amount of gas transferred from the center chamber to each outer chamber was nearly constant and increased only slightly with feed gas rate to the center chamber. For the gas feed rates tested, the percentage of gas fed to the center chamber that transferred to each outer chamber was low, ranging from 1.2 to 4.9 percent. The results of this study are significant to the further development of the "sliding-baffle" microreactor for continuous Fischer-Tropsch synthesis, from a low H₂:CO gas. The microreactor will give important information on the rate of carbon deposition in a system that switches catalyst between two gas atmospheres.

Name thesis:degree_name

M.S.

Level thesis:degree_level

masters

Discipline thesis:degree_discipline

Chemical Engineering

Department dc:contributor.department

Chemical Engineering

Grantor dc:publisher

Virginia Polytechnic Institute and State University

Year dc:date.issued

1987

Author dc:creator

• Briggs, Robert A.

Statement dc:rights

• In Copyright

Licence dc:rights.uri

• http://rightsstatements.org/vocab/InC/1.0/

Language dc:language.iso

en

Handle dc:identifier.uri

http://hdl.handle.net/10919/106149

OAI identifier oai:identifier

oai:vtechworks.lib.vt.edu:10919/106149