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University of Illinois at Urbana-Champaign
The Design of Cyanometallate Cages for Alkali Ion Separation
Abstract
dc:descriptionThe metal sulfide cluster, [(cymene)2Ru3S 2(NCMe)3]2+, reacts with various equivalents of sulfide to give rise to cluster-of-clusters i.e. [(cymene)4Ru 5S4]2+ and [(cymene)6Ru9S 8]2+. The new valence isomer of the [(cymene)4Ru 4S3]2+ was characterized and shown to convert to the black Roussin motif. Finally, this work also demonstrates the potential utility of Ru-S clusters as catalysts for hydrogen production.
Degree
thesis:*- Name thesis:degree_name
- Ph.D.
- Level thesis:degree_level
- Dissertation
- Discipline thesis:degree_discipline
- Chemistry
- Grantor
- University of Illinois at Urbana-Champaign
- Year dc:date
- 2015
Author and committee
dc:creator, dc:contributor.*- Author dc:creator
-
- Kuhlman, Matthew Lee
- Contributors dc:contributor
-
- Rauchfuss, Thomas B.
Subjects
dc:subject × 1Rights
- Language dc:language
- eng
Identifiers
dc:identifier.*- Identifier
- (MiAaPQ)AAI3160908
- OAI identifier oai:identifier
- oai:www.ideals.illinois.edu:2142/84168