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University of Illinois at Urbana-Champaign
Synthesis and Reactivity of ruthenium(VI) and osmium(VI) Nitrido and Imido Complexes
Abstract
dc:descriptionReaction of [N(n-Bu)4][M(N)Me4] with Me3SiOSO2CF3 yielded the neutral complexes Os(NSiMe3)Me4 and Ru(NSiMe3)Me4. These complexes reacted with water to generate Me3SiOH, CH 4, (Me3Si)2O and insoluble metal-containing species. Both reacted with carbon monoxide to form acetone derived from the alkyl ligands. Neither complex reacted with styrene. Trialkyl- and triarylphosphines trapped decomposition products and formed new compounds including Os(N)(PPh3 )Me3 and Os(N)(PMe3)Me3. Mixtures of Os(NSiMe3)Me4, styrene, and N-tosyliminophenyliodinane produced some nitrogen transfer product, cyclo-(tosyl)NCH 2CHPh.
Degree
thesis:*- Name thesis:degree_name
- Ph.D.
- Level thesis:degree_level
- Dissertation
- Discipline thesis:degree_discipline
- Chemistry
- Grantor
- University of Illinois at Urbana-Champaign
- Year dc:date
- 2004
Author and committee
dc:creator, dc:contributor.*- Author dc:creator
-
- Lutz, Christopher Michael
- Contributors dc:contributor
-
- Shapley, Patricia A.
- Shapley, John R.
Subjects
dc:subject × 1Rights
- Language dc:language
- eng
Identifiers
dc:identifier.*- Identifier
- (MiAaPQ)AAI3130974
- OAI identifier oai:identifier
- oai:www.ideals.illinois.edu:2142/84136