Reactions of Organonitrogen Compounds With Unsaturated and Lightly-Stabilized Osmium Carbonyl Clusters

The improved reactivities of the unsaturated cluster hydride H(,2)Os(,3)(CO)(,10) (I) and the "lightly-stabilized" derivative Os(,3)(CO)(,10)(NCCH(,3))(,2) (II) over that of the parent compound Os(,3)(CO)(,12) have been exploited in the preparation of several compounds which would otherwise not be isolable, due to thermal instability at the temperatures required to labilize Os(,3)(CO)(,12).

Name thesis:degree_name

Ph.D.

Level thesis:degree_level

Dissertation

Discipline thesis:degree_discipline

Chemistry

Grantor

University of Illinois at Urbana-Champaign

Year dc:date

2014

Author dc:creator

• Samkoff, Deborah Elizabeth

• Chemistry, Inorganic

Identifier

(UMI)AAI8203575

OAI identifier oai:identifier

oai:www.ideals.illinois.edu:2142/70170