Synthesis and reactivity of organometallic nitridoosmium(VI), ruthenium(VI) complexes

New organometallic osmium(VI) complexes with sulfur and oxygen containing ligands, (Os(N)(CH$\sb2$SiMe$\sb3)\sb2$Y) $\sp-$ $\{$Y = (SCH$\sb2$CH$\sb2$S), (SCN)$\sb2$, (S), (S-C$\sb5$H$\sb4$N), (WS$\sb4$), (MoS$\sb4$), (SO$\sb4$), (CO$\sb3$), (ReO$\sb4)\sb2\}$ were prepared. Two crystal structures of (Os(N)(R)$\sb2$(SC$\sb5$H$\sb4$N)) $\sb2$, (NBu$\sp{\rm n}\sb4$) (Os(N)(R)$\sb2$(WS$\sb4$)) (R = CH$\sb2$SiMe$\sb3)$ were determined.

Name thesis:degree_name

Ph.D.

Level thesis:degree_level

Dissertation

Discipline thesis:degree_discipline

Chemistry

Grantor

University of Illinois at Urbana-Champaign

Year dc:date

2011

Author dc:creator

• Zhang, Naijie

Contributors dc:contributor

• Shapley, Patricia A.

• Chemistry, Inorganic
• Chemistry, Organic

Statement dc:rights

• Copyright 1991 Zhang, Naijie

Language dc:language

eng

Identifier

AAI9211056
(UMI)AAI9211056

OAI identifier oai:identifier

oai:www.ideals.illinois.edu:2142/20352