Investigation of ligand misdirection using the kinetic element effect and the kinetic enthalpy effect.

Metal complexes were synthesized with the atropisomeric dabp. X-ray crystal structures were solved for [Ru(bipy)2(dabp)]2+ and [(eta6-C6H6)Ru(dabp)(Cl)]+. Only one diastereomer was observed for [Ru(bipy)2(dabp)] 2+ in the 1H NMR spectrum. Exchange was observed and measured for the ruthenium and osmium complexes of [(eta6-C 6H6)M(dabp)(Cl)]+.

Author dc:creator

• Alguindigue, Susan Stanislav.

Advisor dc:contributor.advisor

• Ashby, Michael T.,

• Molecular orbitals.
• Ligand binding (Biochemistry) g
• Crystal field theory.
• Chemistry, Inorganic.

Handle dc:identifier.uri

http://hdl.handle.net/11244/5968

OAI record oai:identifier

https://shareok.org/server/oai/request?verb=GetRecord&metadataPrefix=dim&identifier=oai%3Ashareok.org%3A11244%2F5968