Novel methods for fabrication of non-close-packed structures through colloidal self-assembly

Colloidal dispersions are usually stabilized by interparticle electrostatic repulsion. However, strong electrostatic potentials prevent nucleation of new structures. When the electrostatic potential is strongly attractive, particles coagulate into a disordered structure; if it is strongly repulsive, known processes can order them into a closepacked structure. Driven by the need to make tailored structures, researchers have focused on circumventing electrostatics to nucleate and stabilize newer structures. Yet most colloidal systems of interest are strongly charged. Reducing the electrostatic potential of a system may create only unstable structures without long-range order. In this thesis, electrostatic interaction between strongly charged particles is exploited to make novel structures. It is shown that -with an added steric component in the interaction potential- oppositely charged particles, which undergo rapid coagulation otherwise, can be arranged into stable, long-range ordered structures. Compared to their like-charged counterparts, these structures have greater stability due to an attractive electrostatic potential. It is shown that an entire class of surfactants, amphiphilic non-ionic surfactants, can be used to stabilize an oppositely charged particle system. Stabilizing these systems, allows for the nucleation of newer structures. For instance, it is shown that a non-close-packed arrangement of positive particles can be obtained on a layer of negatively charged particles. Creating such non-close-packed 2D structures on a template is essential for creating 3D non-closepacked structures. Indeed, it is shown that at high Debye lengths, by varying the concentration of particles in a suspension of like-charged colloids, electrostatic repulsion among particles can stabilize "sparse" structures. In these structures, particles occupy only a few of the many sites that are available to them. Yet, they form an ordered structure. Nuclei of a sparser structure are assembled at higher Debye length and lower particle concentration. Monte Carlo simulations confirm that these structures are stabilized by electrostatic repulsion when particle concentration is low. It is shown that the remaining sites in a sparse structure can be filled by a different particle type. By replicating this process of 2D heterostructure formation, layer by layer, and removing one kind of particle in the last step of the process, a two-layer non-close-packed structure is obtained.

Department dc:contributor.department

Massachusetts Institute of Technology. Dept. of Materials Science and Engineering.

Grantor dc:publisher

Massachusetts Institute of Technology

Year dc:date.issued

2010

Author dc:creator

• Sharma, Vyom

Advisor dc:contributor.advisor

• Yet-Ming Chiang and W. Craig Carter.

• Materials Science and Engineering.

Statement dc:rights

• M.I.T. theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission. See provided URL for inquiries about permission.

Licence dc:rights.uri

• http://dspace.mit.edu/handle/1721.1/7582

Language dc:language.iso

eng

Handle dc:identifier.uri

http://hdl.handle.net/1721.1/59710

OAI identifier oai:identifier

oai:dspace.mit.edu:1721.1/59710