The role of hydrogen in the growth of carbon nanotubes : a study of the catalyst state and morphology

The role of hydrogen in chemical vapor decomposition (CVD) of C2H4 for growth of carbon nanotubes (CNTs) was investigated. Fe/A1203 (1/10 nm) catalyst layers were used for growth on Si substrates and the times at which H2 was introduced during the 40 minute temperature ramp, 15 minute annealing (without C2H4), and 15 minute growth (during which C2H4 was flowing) stages was varied. When H2 was introduced before heating, CNTs grew to a length of [approx.] 0.3 mm. However, CNT growth was severely suppressed when H2 was introduced at different points during temperature ramp. Recovery of CNT growth was observed when H2 was introduced during the annealing and growth stages. Under optimum conditions, an [approx.] 1 mm thick carpet of CNTs could be obtained. The chemical state and morphology of the catalysts as a function of the time of H2 introduction were examined using XPS and AFM, respectively. We found that the as-deposited state of Fe was an iron oxide, due to reaction with 02 in the atmosphere, and that the H2 reduced the iron oxide to different oxidation states, depending on the time of H2 introduction. AFM inspection showed that surface roughness could also be correlated with areas of vertical CNT growth.

Department dc:contributor.department

Massachusetts Institute of Technology. Dept. of Materials Science and Engineering.

Grantor dc:publisher

Massachusetts Institute of Technology

Year dc:date.issued

2006

Author dc:creator

• Kim, Jin Suk Calvin

Advisor dc:contributor.advisor

• Carl V. Thompson.

• Materials Science and Engineering.

Statement dc:rights

• M.I.T. theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission. See provided URL for inquiries about permission.

Licence dc:rights.uri

• http://dspace.mit.edu/handle/1721.1/7582

Language dc:language.iso

eng

Handle dc:identifier.uri

http://hdl.handle.net/1721.1/35064

OAI identifier oai:identifier

oai:dspace.mit.edu:1721.1/35064