ΣΥΝΘΕΣΗ, ΔΟΜΗ ΚΑΙ ΤΕΧΝΟΛΟΓΙΚΗ ΕΦΑΡΜΟΓΗ ΝΕΩΝ ΜΙΚΤΩΝ ΣΥΜΠΛΟΚΩΝ ΒΟΡΙΟΥ ΜΕ Β-ΔΙΚΕΤΟΝΕΣ ΚΑΙ ΟΡΓΑΝΙΚΑ ΔΙΚΑΡΒΟΝΙΚΑ ΟΞΕΑ Η ΥΔΡΟΞΕΑ

THIRTY THREE NEW BORON COMPLEXES WITH B-DIKETONES AND ORGANIC HYDROXYACIDS AND SIXTEEN NEW BORON COMPLEXES WITH B-DIKETONES AND ORGANIC DICARBOXYLIC ACIDS WERE PREPARED. THEIR STRUCTURE WAS DEFINED WITH ANALYTICAL, SPECTROSCOPIC AND X-RAY METHODS. IT WAS CONFIRMED THAT THE BORON ATOM IS CONJUCTED TETRAEDRICALLY WITH ONE LIGAND OF SIX MEMBERED RING WHICH COMES FROM B-DIKETONE AND ONE LIGAND OFFIVE MEMBERED OR SIX MEMBERED RING WHICH COMES FROM THE CORRESPONDING ORGANIC ACID. DURING THE RESEARCH OF NMR SPECTRA-1H AND 13C- THE FUNCTION OF THE PHENOMENON "LONG RANGE CURRENT EFFECT" WAS OBSERVED IN BOROSPIRANIC COMPOUNDS. SOME OF THE NEW COMPOUNDS CAN BE APPLIED: A. AS CATALYSTS IN BITUMEN OXIDATION, B. ASBACTERIOSTATIC AGENTS.

Grantor dc:publisher

Aristotle University Of Thessaloniki (AUTH)

Year dc:date

1987

Author dc:creator

• Οικονόμου, Νίκος

• Β-δικετόνες
• Βόριο
• ΟΡΓΑΝΙΚΑ ΔΙΚΑΡΒΟΝΙΚΑ ΟΞΕΑ
• ΟΡΓΑΝΙΚΑ ΥΔΡΟΞΥΟΞΕΑ
• Σύμπλοκα
• B-diketones
• Complexes
• ORGANIC DICARBOXYLIC ACIDS
• ORGANIC HYDROXYACIDS
• Επιστήμες Μηχανικού και Τεχνολογία
• Επιστήμη Πολιτικού Μηχανικού
• Engineering and Technology
• Civil Engineering

Language dc:language

gre

Identifier

10.12681/eadd/0568

OAI identifier oai:identifier

oai:10442/0568